CS274418B2 - Polymer composition with self-quenching properties - Google Patents
Polymer composition with self-quenching properties Download PDFInfo
- Publication number
- CS274418B2 CS274418B2 CS998087A CS998087A CS274418B2 CS 274418 B2 CS274418 B2 CS 274418B2 CS 998087 A CS998087 A CS 998087A CS 998087 A CS998087 A CS 998087A CS 274418 B2 CS274418 B2 CS 274418B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- weight
- dicyandiamide
- polymer composition
- component
- bismuth
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 26
- 229920000642 polymer Polymers 0.000 title claims description 12
- 238000010791 quenching Methods 0.000 title 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical group NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims abstract description 23
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical group NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920000877 Melamine resin Chemical group 0.000 claims abstract description 15
- 150000001412 amines Chemical class 0.000 claims abstract description 15
- -1 antimony halides Chemical class 0.000 claims abstract description 13
- 239000003063 flame retardant Substances 0.000 claims abstract description 12
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 8
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 7
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 7
- 150000001875 compounds Chemical group 0.000 claims abstract description 6
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 6
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052794 bromium Chemical group 0.000 claims abstract description 3
- 239000000460 chlorine Substances 0.000 claims abstract description 3
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 3
- 125000001309 chloro group Chemical group Cl* 0.000 claims abstract description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 8
- 229920001155 polypropylene Polymers 0.000 claims description 8
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 7
- NJYZCEFQAIUHSD-UHFFFAOYSA-N acetoguanamine Chemical compound CC1=NC(N)=NC(N)=N1 NJYZCEFQAIUHSD-UHFFFAOYSA-N 0.000 claims description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- 239000003999 initiator Substances 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 3
- 150000001451 organic peroxides Chemical group 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 229920001198 elastomeric copolymer Polymers 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical group C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 abstract 2
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical group NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 abstract 1
- JJWCTKUQWXYIIU-UHFFFAOYSA-N 2-Benzimidazolylguanidine Chemical group C1=CC=C2NC(N=C(N)N)=NC2=C1 JJWCTKUQWXYIIU-UHFFFAOYSA-N 0.000 abstract 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical group CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 abstract 1
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 10
- 229910001507 metal halide Inorganic materials 0.000 description 9
- 150000005309 metal halides Chemical class 0.000 description 9
- TXKAQZRUJUNDHI-UHFFFAOYSA-K bismuth tribromide Chemical compound Br[Bi](Br)Br TXKAQZRUJUNDHI-UHFFFAOYSA-K 0.000 description 8
- 239000000155 melt Substances 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 241000219112 Cucumis Species 0.000 description 5
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 4
- RPJGYLSSECYURW-UHFFFAOYSA-K antimony(3+);tribromide Chemical compound Br[Sb](Br)Br RPJGYLSSECYURW-UHFFFAOYSA-K 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 238000007363 ring formation reaction Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- PVKCVCDTYNNNOG-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-triamine;hydrobromide Chemical compound [Br-].NC1=NC(N)=[NH+]C(N)=N1 PVKCVCDTYNNNOG-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 description 2
- 229940052810 complex b Drugs 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000004445 quantitative analysis Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- AQHVVFDSURVEDC-UHFFFAOYSA-N (2,3-dimethyl-2-phenylhexan-3-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)C(C)(CCC)C1=CC=CC=C1 AQHVVFDSURVEDC-UHFFFAOYSA-N 0.000 description 1
- FANGQVKSFHFPBY-UHFFFAOYSA-N 2-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound OC(=O)C(C)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 FANGQVKSFHFPBY-UHFFFAOYSA-N 0.000 description 1
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000002656 Distearyl thiodipropionate Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 150000001622 bismuth compounds Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 1
- 235000019305 distearyl thiodipropionate Nutrition 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/90—Antimony compounds
- C07F9/902—Compounds without antimony-carbon linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/94—Bismuth compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/59—Arsenic- or antimony-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT8622887A IT1213442B (it) | 1986-12-30 | 1986-12-30 | Complessi degli alogenuri di bismuto o antimonio con ammine. |
| IT8622888A IT1213443B (it) | 1986-12-30 | 1986-12-30 | Composizioni polimeriche dotate di migliorate caratteristiche di autoestinguenza alla fiamma. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS998087A2 CS998087A2 (en) | 1990-09-12 |
| CS274418B2 true CS274418B2 (en) | 1991-04-11 |
Family
ID=26328284
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS998087A CS274418B2 (en) | 1986-12-30 | 1987-12-28 | Polymer composition with self-quenching properties |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US4798857A (en]) |
| EP (1) | EP0273458B1 (en]) |
| JP (1) | JP2705938B2 (en]) |
| KR (2) | KR910007945B1 (en]) |
| CN (1) | CN1011241B (en]) |
| AR (1) | AR246507A1 (en]) |
| AT (1) | ATE86608T1 (en]) |
| AU (1) | AU598620B2 (en]) |
| BR (1) | BR8707100A (en]) |
| CA (1) | CA1307789C (en]) |
| CS (1) | CS274418B2 (en]) |
| DE (1) | DE3784674T2 (en]) |
| ES (1) | ES2053518T3 (en]) |
| FI (1) | FI88290C (en]) |
| IN (2) | IN168672B (en]) |
| NO (1) | NO173505C (en]) |
| RU (1) | RU1833397C (en]) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2635781A1 (fr) * | 1988-08-24 | 1990-03-02 | Atochem | Compositions ignifugeantes pour resines synthetiques a base de composes halogeno-metalliques azotes et resines synthetiques renfermant lesdits composes |
| US4954551A (en) * | 1989-03-31 | 1990-09-04 | Ethyl Corporation | Halogen-containing organometallic compounds |
| US5041576A (en) * | 1989-12-07 | 1991-08-20 | Wasfi Sadio H | Antimony oxo-metalate complexes |
| IT1243862B (it) * | 1990-10-23 | 1994-06-28 | Himont Inc | Concentrati non estrusi di additivo antifiamma e processo per la loro preparazione. |
| IT1271419B (it) * | 1993-08-11 | 1997-05-28 | Himont Inc | Composizioni per fibre poliolefiniche aventi migliorate caratteristiche di resistenza alla fiamma ed assenza di corrosivita' |
| KR100774819B1 (ko) * | 2006-07-20 | 2007-11-07 | 주식회사 엘지화학 | 난연성이 우수한 열가소성 수지 조성물 |
| US20160312121A1 (en) * | 2013-10-02 | 2016-10-27 | Empire Technology Development Llc | Bromine-free fire retardant (fr) agents capable of using a cyclization mechanism |
| EP3015461B1 (en) | 2014-10-27 | 2017-08-30 | Sichim Alfa S.r.l. | Preparation process of a flame redardant composition made from brominated bismuth and/or antimony compounds complexed with melamine and composition obtained thereby |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3280030A (en) * | 1963-09-10 | 1966-10-18 | Texaco Inc | Lubricating composition |
| US3705128A (en) * | 1971-07-23 | 1972-12-05 | Du Pont | Flame resistant polymers containing amide complexes of metal salts |
| US3850882A (en) * | 1971-12-01 | 1974-11-26 | Phillips Petroleum Co | Flame retarded compositions and additive systems therefor |
| US4028333A (en) * | 1975-12-18 | 1977-06-07 | Velsicol Chemical Corporation | Flame retardant polymeric compositions containing melamine hydrohalides |
| IT1088155B (it) * | 1977-10-27 | 1985-06-10 | Montedison Spa | Composizioni polimeriche autoestinguenti a base di polipropilene modificato |
| US4264364A (en) * | 1979-10-11 | 1981-04-28 | Indian Head Inc. | Thermally stable smoke suppressant additives to polymeric compositions |
-
1987
- 1987-12-23 JP JP62326650A patent/JP2705938B2/ja not_active Expired - Fee Related
- 1987-12-28 FI FI875723A patent/FI88290C/fi not_active IP Right Cessation
- 1987-12-28 CS CS998087A patent/CS274418B2/cs not_active IP Right Cessation
- 1987-12-28 IN IN999/CAL/87A patent/IN168672B/en unknown
- 1987-12-29 BR BR8707100A patent/BR8707100A/pt not_active IP Right Cessation
- 1987-12-29 NO NO875466A patent/NO173505C/no not_active IP Right Cessation
- 1987-12-29 RU SU874203961A patent/RU1833397C/ru active
- 1987-12-29 CA CA000555533A patent/CA1307789C/en not_active Expired - Fee Related
- 1987-12-29 AR AR87309714A patent/AR246507A1/es active
- 1987-12-29 AU AU83088/87A patent/AU598620B2/en not_active Ceased
- 1987-12-30 ES ES87119394T patent/ES2053518T3/es not_active Expired - Lifetime
- 1987-12-30 US US07/139,420 patent/US4798857A/en not_active Expired - Lifetime
- 1987-12-30 AT AT87119394T patent/ATE86608T1/de not_active IP Right Cessation
- 1987-12-30 CN CN87108353A patent/CN1011241B/zh not_active Expired
- 1987-12-30 DE DE8787119394T patent/DE3784674T2/de not_active Expired - Lifetime
- 1987-12-30 EP EP87119394A patent/EP0273458B1/en not_active Expired - Lifetime
- 1987-12-30 KR KR1019870015444A patent/KR910007945B1/ko not_active Expired
-
1990
- 1990-12-10 IN IN1019/CAL/90A patent/IN171450B/en unknown
-
1991
- 1991-08-10 KR KR1019910013825A patent/KR920002234B1/ko not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ES2053518T3 (es) | 1994-08-01 |
| FI88290C (fi) | 1993-04-26 |
| JPS63253094A (ja) | 1988-10-20 |
| US4798857A (en) | 1989-01-17 |
| JP2705938B2 (ja) | 1998-01-28 |
| EP0273458B1 (en) | 1993-03-10 |
| AU598620B2 (en) | 1990-06-28 |
| FI88290B (fi) | 1993-01-15 |
| IN168672B (en]) | 1991-05-18 |
| NO173505C (no) | 1993-12-22 |
| BR8707100A (pt) | 1988-08-02 |
| NO173505B (no) | 1993-09-13 |
| CN87108353A (zh) | 1988-08-24 |
| KR910007945B1 (ko) | 1991-10-04 |
| CN1011241B (zh) | 1991-01-16 |
| IN171450B (en]) | 1992-10-17 |
| AR246507A1 (es) | 1994-08-31 |
| FI875723L (fi) | 1988-07-01 |
| AU8308887A (en) | 1988-06-30 |
| EP0273458A2 (en) | 1988-07-06 |
| ATE86608T1 (de) | 1993-03-15 |
| DE3784674D1 (de) | 1993-04-15 |
| NO875466D0 (no) | 1987-12-29 |
| CS998087A2 (en) | 1990-09-12 |
| EP0273458A3 (en) | 1990-05-30 |
| CA1307789C (en) | 1992-09-22 |
| KR880007635A (ko) | 1988-08-29 |
| FI875723A0 (fi) | 1987-12-28 |
| KR920002234B1 (ko) | 1992-03-20 |
| NO875466L (no) | 1988-07-01 |
| RU1833397C (ru) | 1993-08-07 |
| DE3784674T2 (de) | 1993-09-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| IF00 | In force as of 2000-06-30 in czech republic | ||
| MM4A | Patent lapsed due to non-payment of fee |
Effective date: 19991228 |